There is an excellent and reasonable current summary of information related to paper preservation at: http://www.clir.org/pubs/reports/pub95/contents.html The article is called, "Preservation Science Survey -- An Overview of Recent Developments in Research on the Conservation of Selected Analog Library and Archival Materials" written is December 2000 and published in cooperation with the European Commission on Preservation and Access. Chapter 2 is devoted to paper. One interesting note seems to say that even "acid free" paper will not stay that way long. The article notes, in part: "Formation of acids" "While it is well known that papers become more acid with age, it is generally assumed that this declining pH does not significantly contribute to the degradation of paper. It is often presumed that only the acids introduced in the manufacture of paper and those absorbed from the environment are responsible for the deterioration of paper. In this context, the term "acid-free," which in effect equates neutral and alkaline papers, is often used to imply permanence. However, the spontaneous formation of acids in cellulose during aging cannot be overlooked as a cause of paper degradation." ... "[N]eutral papers cannot remain acid-free for long. Weak acids formed in the degradation of cellulose and hemicelluloses have generally been considered not to pose as significant a threat as do stronger acids introduced from acidic alum-rosin size or those formed by absorption of oxides of nitrogen and sulfur from the environment. However, the present findings suggest that these weak acids accumulate at a sufficiently high rate to contribute significantly to the increasing acidity in paper as it ages. Alkaline papers showed appreciably higher [Is this a typo?-PR] rates of accumulation than did other papers, since the acids formed are immediately neutralized and cannot enter into other reactions or dissipate. It was also shown that these weak acids attach themselves strongly enough to paper, probably by hydrogen bonding, that they are not easily dislodged from the paper matrix, even upon airing. Because of this tenacity and because they catalyze their own formation, these acids present a constantly escalating source of damage that can be dealt with only through deacidification." Paul http://www.PaulRoark.com
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Deacidification -- It's not just for EAM
2002-09-23 by Paul Roark
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