Acid-free glossy paper
2004-03-26 by Paul Roark
Short version: We may be able to make any glossy paper - also known as RC or "barrier" papers - "acid free" and perhaps archival by spraying the back with Wei T'o deacidification spray. (See http://www.weito.com/intro.htm) Long version: The Epson premium glossy papers are rated by Wilhelm as having a dark storage life of ">200" years, just like the best cotton papers. Most glossy papers are not rated so highly. When I test the Epson premium papers for acidity with my Abbey acid test pen, the difference I see is that the interior fibers are alkaline - buffered paper. The interior papers of all other glossy papers I've tested are acidic - not buffered. It is typically the acids from lignin that limit paper life. That is why EEM is not rated very highly - the paper doesn't last as long as the image. It appears that the Wei T'o deacidification spray penetrates the back side of these papers and buffers the interior fibers, but is stopped by the resin (polyethylene) barrier from reaching the surface. One of the problems with the deacidification sprays is balancing the goal of buffering the paper fibers with the conflicting desire to not touch the surface of the print and pigments. The buffers may lessen the dmax and might cause the image to yellow faster with light exposure. One type of deacidification spray (Bookkeeper by Preservation Technologies) does not penetrate paper at all. If the paper is sprayed on the back, this protects the image, but it also does not get the buffer into the paper where the lignin acid source is. (Bookkeeper just puts little magnesium oxide particles on the back of the paper as if they were pigments.) The theory of Bookkeeper is that acids migrate enough to be mopped up by buffers that are close. However, in my tests on EEM the interior papers never did stop testing as acidic. Another type of deacidification spray - Wei T'o - has the buffer (magnesium carbonate) dissolved in a solvent. With this spray the buffer is pulled into the paper by the solvent (alcohol and some others), where it can be more effective. Wei T'o makes different versions of the spray with different solvents that carry the buffer differing distances into the paper. I have #12, which carries the buffer into the thickest papers. The problem with this approach on matte papers is that the solvent carries the buffer right up into the inkjet coating and image. In fade testing I detected more yellowing in the test strip sprayed with Wei T'o than in a control test strip. The principal of Wei T'o has also warned that the coatings could be complex systems where the effects of the buffer might be unpredictable. We probably just do not want the buffer to get into the coating and image. So, what about glossy, "barrier" papers? Will the Wei T'o penetrate the back of the paper but be stopped by the RC barrier? It appears that many if not most inkjet RC papers have the resin - polyethylene - just between the coating and the paper base - unlike photographic RC papers that have polyethylene on both sides of the paper. I noticed with the roll of Glossy Paper Heavyweight I was testing that a spray of water on the back would take the curl out of it. This would not happen if the back were polyethylene. Since the barrier is to stop the water in the ink from reaching the paper base, and these prints are not processed in a tray of water like photographic RC papers, it does make sense that only one side would need a barrier. I have now tried the Wei T'o spray on the backs of several glossy papers, including Epson Glossy Photo paper and Ilford Galerie Smooth Pearl. These are two of my favorite cheap glossy papers, but they have acidic paper interiors that will limit their lives. The Wei T'o does penetrate the backs of the glossy papers I've tried. With the 2 papers above, the interior fibers tested as very alkaline after spraying, just like the Epson Premium glossy papers. But, with the Epson Glossy Photo Paper, I could not tell if the Wei T'o had also penetrated the barrier and polluted the surface. This is because the Glossy Photo paper has an alkaline surface to start with. The Ilford Pearl, however, like the Epson Premium papers, has an acidic surface. (This correlates with a higher dmax.) So, if the Wei T'o penetrated the barrier, it would turn the surface alkaline - It did not. Thus, the Ilford paper may have been effectively buffered without the coating and image being affected because the polyethylene barrier kept the Wei T'o in the paper and away from the coating. In short, the Wei T'o spray may make the cheap and good looking glossy papers acid free. This could extend their lives very significantly (many times). I'll have to fade test some samples as soon as my current test is over (which will be more than a month from now). This could be rather significant - cheap, acid-free glossy paper. The Epson Glossy Photo paper is even bronzing free. Now if we could just find a thicker version of that . Paul www.PaulRoark.com <http://www.paulroark.com/> [Non-text portions of this message have been removed]