[Digital BW] Re: Piezo v. MIS variable-tone versions
2001-08-12 by Paul Roark
Bernd, You wrote: >... IRIS prints, they did not only warm up, but >had different color shiftings in different areas of the image. That's not good at all. At least our inkjets seem to warm uniformly. >...I'm a silver printer too. I used to print on Agfa >Multicontrast Classic (Baryt). It is warm-toned in neutral >developers, but can be much warmer than Piezo in warmtone developers. I used Dektol with it for some time. I found, however, that I preferred the cooler Kodak Polymax Fine Art. When toned just a few minutes in selenium 1:19, the print ends up very neutral. My scanner shows the print to be about 1 unit warm (yellow). >I\ufffdm very curious whether I will switch to cooler tones with your >variable inks I ordered for my 1270. Maybe I\ufffdll fall in love with the >cooler tones if I see my industrial landscapes printed with MIS inks?! I think just due to the novelty of it I was printing quite cool at first. I've now backed off to what I call neutral -- it's actually 4 units cool (blue). (That is, the Blue channel of the RGB readings on my scanner is 4 units above the Red channel reading. I'll have to do more homework to understand the HSB model.) I have the "neutral" tone set there anticipating some warming. That tone seems to look very good hanging next to my Kodak Polymax prints. >Paul, what do you mean with dyes/pigments? Doesn\ufffdt Jon Cone claim his >inks are pure carbon pigments?? Or did I MISunderstand something? Jon acknowledges that there are some dyes in the mix. All of these pigmented inksets have some "dyes" in them. However, he has declined to give us any specific percentage of his mix that is dye. Bob Zeiss at MIS has said that MIS inks are about .5% dye. He explains that all the desktop pigments are carbon based. (Some large format, less photographic printers use large particles of pure pigment. However, those pigments cannot, apparently, be ground fine enough for the desktop/photo-realistic printers, and the gamut is not very good.) Because carbon is a warm brown color, the carbon particles are then coated with a colorant -- black for the black, color for the color. This is what Bob calls the "dyes" in his mix. And, I've gotten the impression this is the only dye in MIS. Some pigmented inksets, however, actually have some dyes in solution that are not just a coating on the carbon particle. I think the blackness of Generations Enhanced black is achieved this way. I think Piezo is also in this group. If you take a drop of Piezo magenta-position gray, for example, and put it on a Kleenex or paper towel so that it will spread, you will see the colors separate. (I remember doing chromatography in high school chemistry -- the same principle, I'd guess.) The Piezo ink splotch will end up looking very dark in the center, but it will have a fringe of what looks green-blue to me. I think what this might be showing is the separation of the dye from the pigment. I would expect the dye to migrate further through the paper. If you take a drop of the MIS variable-tone/mix magenta-position ink, which is the same density as the Piezo magenta-position gray, and you do the same thing, you do not get a color fringe. Maybe this is because MIS inks do not have color dyes in them. Keep in mind that I'm not a chemist with any sophisticated method of testing all these inks. I'm just summarizing my understanding of what is going on based on what I've been told, read, and observed in my own experimenting. Of course, what I've been told by many is not necessarily consistent -- nor are all of my own experiments -- so I always reserve the right to say I was wrong. Paul http://www.PaulRoark.com