On Mon, 1 Aug 2016 05:45:53 +0200, you wrote: >RoHS allows 0.1% lead. > >I think this Liquid Tin is based on thiourea, something much, much worse >than lead. Remember to wash your hands and wear a hardhat or something ;-). I think it is. It comes with lots of warnings, most of which involve the word "poison". I use gloves and tongs, and wash the boards thoroughly. Also, this is done quite outside the house. Wonder if I could do something like HASL.... Harvey > >ST > >On Sun, Jul 31, 2016 at 9:37 PM, Harvey Altstadter hrconsult@... >[Homebrew_PCBs] <Homebrew_PCBs@yahoogroups.com> wrote: > >> >> This is the problem with the ROHS directive being in absolutes. A mere >> pinch of lead would do away with the whisker problem in it's entirety. >> >> I am not familiar with the Liquid Tin product, but if it leaves any >> elemental tin (not oxide), then it can be a source of whiskers. I suspect >> that this is the same thing that the industry calls immersion tin. That >> process is a chemical replacement where the liquid is a tin salt, and the >> reaction exchanges the copper for tin, leaving elemental tin on the >> surface, with the copper going into solution as a copper salt. Clean copper >> quickly oxidizes, making soldering to the board difficult to impossible. >> The purpose of immersion tin is to keep the surface solderable when the >> board is not immediately used. It is an identified source of whiskers. >> http://www.epectec.com/articles/pcb-surface-finish-advantages-and-disadvantages.html >> I hope this answers all your questions. >> >> Harvey >> On 7/31/2016 9:48 AM, alan00463@... [Homebrew_PCBs] wrote: >> >> >> >> Thanks, Brad. I watched the NASA video. >> >> No, Harvey A., my circuit has no glass diodes, or other components that I >> know to contain glass. >> >> I am glad you mentioned condensation, as I had never thought of >> it occuring on my circuit board. Having just defrosted my freezer yester >> day, I know it grows quickly on cold surfaces. Since my circuit con- >> troller will always be outdoors while in use, I will keep it inside when >> not in use, so that condensation doesn't happen. Nonetheless, I will >> inspect the PCB for condensation when the outdoor temperature drops. The >> only "spray" the box might be subjected to is rain, which is distilled >> water. The box will be on my screened-in wooden porch. The porch was >> built with pressure-treated wood many years ago, but for the past several >> years moss has been growing on the wood, which should tell you how damp it >> is. (Another project--re-waterproofing the wooden porch.! Will probably >> need another recommendation for treating that wood too, but email me >> privately for that.) >> >> Okay, copper oxidation won't degrade the circuit's performance. >> >> What about tin oxide? Does either Liquid-Tin coating or leaded >> solder contain tin? If yes, do you think tin oxide will degrade the >> circuit's >> performance ? Or is too "self-limiting" and of no consequence? >> >> I am not sure what you meant by the "Polyurethane wood polish" you >> recommend. I am trying to identify a furniture polish containing >> polyurethane. So far, I am only finding furniture polishes designed for >> wood furniture that has a top coat of polyurethane, like the one on your >> local tavern's wooden bar top. I'm not sure whether to look for a >> furniture polish that was designed to be applied to a polyurethane top >> coat, or that actually contains polyurethane as listed in the >> ingredients. Or are they one and the same? As you can tell, I am >> pretty much ignorant about this product. I am guessing its purpose is to >> fill in surface scratches on a polyurethane top coat. >> >> 73 to all. >> >> >> >> >>
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Re: [Homebrew_PCBs] Preventing oxidation of copper outdoors
2016-08-01 by Harvey White
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