Well, I finaly got around to buyng a jug of acid and trying this out. I bought a gallon of HCL (31.25%) from my local hardware store, $2.95 (USD) Stopped by the Pharmacy and bought a quart of 3% H2O2 for $0.94. Plastic container, about 1/4 cup acid, stuck in a piece of circuit board and started adding H2O2. At about 1/2 cup I could see some green tinge and the copper started changing. I poured in a litle more (about 3/4 cup total) and the copper etched in about 8 minutes. About 1 cup total of etchant removed about 30 sq inches of copper (surplus scrap, but I think 1 oz) before it was quite dark and slowed considerably. I think the amount of water in medical grade would prevent it being used to recharge the etchant (to much dilution) but it certainly started it fine. Even if I had to throw it away instead of recharging it, this is still *much* cheaper than Feric Chloride. At these ratios a 94 cent quart of medical H2O2 and a cup of acid would replace a $12 quart of Feric Chloride. I did notice that it was much more unpleasant to be around (lots of nasty fumes) But I can work around that. Thanks -Denny --- In Homebrew_PCBs@yahoogroups.com, Stefan Trethan <stefan_trethan@g...> wrote: > On Tue, 06 Jan 2004 05:28:53 -0000, dkesterline <desterline@t...> wrote: > > >> for a start you make a 15% HCl solution (tap water is fine) > >> > > Like 850cc water and 150cc hydrochloric acid? (clearifing weight / > > volume, and initial strength of the acid.) > > i did it by volume, it is not critical. > i think the recepie i read was 12% by volume. > it doesn't change much. > > many recepies call for 30% HCl diluted 1:1 (volume) with water. > i think i did exactly that. > > As it was said you can keep the acid amount low, and only let the CuCl2 do > all the > work. but then you might experience the "blue" effect more often. > > > > >> Then you put a pcb in it. > >> > > One you want to etch, or just some scrap to start the proccess? > > one you want to etch. > but you can try it with scrap if you have too much ;-) > no, it workes like always, also with the first pcb. > i used the first one. > > > > >> then you put H2O2 in it. > >> for the first pcb you may need more than usual. > > > > Approx how much? (please specify strength for that amount) > > I don't remember clearly. > if you have have 250ml etchant the smallest amount you can pour out of the > bottle will do. > maybe a teaspoon full, or two. > start slow, if it doesn't work use more, agitate in between. > > > > > > Any attempt to remove the copper in the long run? Or do you dispose and > > start over every so often? > > > no attempt yet. > maybe some electroplating could work. > but maybe all you get is cloring gas.... > > i think it would require carbon electrodes, stainless steel is definitely > etched (ask the sink, now it has "freckles" where the tiny splatters around > the > bowl landed...) > > > >> For me this etchant is ideal with toner transfer - as it is as easy > > and > >> fast. > >> the toner takes no harm in the etchant. > >> photoresist works too. > >> Most ohp markers (edding etc) don't work too well. > >> the best is the red staedtler ohp pen ink. > > > > (assuming ohp = overhead projector) I thought OHP makers were water > > based. I've always used permanent markers like sharpies for this job. > > (though my toner transfer is almost good enough to not need it anymore :-) > > > > i used it once in my first 5 or so toner transfer boards. > and then it was for the board outline ;-). > > > I'm probably being overly analytical about this, it's likley the proccess > > is more forgiving and tolerant. But it's better to before I stir up a > > mess. > > > > i think so.. > the german recepies are rather crude, and i am always up for experiments... > > > wear the proper protective things, goggles and maybe gloves. > old clothes maybe, but if you mess around enough to stain your clothes > maybe this is not the best thing to do... > > but still - even if you ruin your clothes, not much harm done, > if you ruin your eyes - you can't dispose of them and wear a new pair. > so take the google thing serious. > > Stefan > > > Thanks > > -Denny > > > >
Message
Re: Etching Chemicals
2004-01-08 by dkesterline
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