Hi Denny, As I had mentioned in my post a 50-50 mix was IMHO way too strong, and I had realized that while I was combining - at this point I was still in a big guessing game (I only wish I were a chemist sometimes, would have made some of this make much more sense and I probably would have known the info presented to me was off, and that even my 33/67 was off).... <snip> The mixture on the site I had read was 50% H2O2 to 50% muriatic acid. THIS MIX IS TOO STRONG. I mixed at ~33% acid to 67% h2o2 and it was still strong enough to etch a 4.5x7 board of mostly copper </snip> I also mentioned that I felt a smaller ratio would work just as well... <snip> I think a much weaker mix with a longer etch time is desireable, I'd rather do a 1 to 4 or perhaps a 1 to 5 mix </snip> 1 to 5 is a 20% ratio of acid to the remaining components of the mix - so that isn't too far off from 15%. I'm glad to hear about the even lower then I figured mixture ratio. I do see why I didn't find anything - I spell the acid Muriatic - which is the only way I have ever known how to spell it (see msds: http://www.aldenleeds.com/html/muriatic.html) - I now see that it can be spelled differently by people (muratic) - searching thru the emails with muratic as a spelling would have given the results you spoke of. I honestly didn't know it combined to do cupric chloride etching - Thank you for that extra piece of info, I wish I had known about it before, I could have forgone some of the bad mixture ratio sites, and a search on cupric chloride etching would have resulted in a lot more accurate info I believe (plus, I wouldn't have posted a long note on something that had just been gone over recently, oh well, my bad). Also the previous sites I had read this on had talked about just a mixture of the acid with h2o2, now that I've been able to read a bit more from some of the links, as well as the now found previous discussion I understand more and find myself with a ton of extra h2o2 rofl. -Tony > The basic jist is 15% Muratic (hydrochloric) acid and about 2% H2O2. > This isn't the acid etching, it's Cupric Chloride. The free oxygen in > the H2O2 breaks the hydrogen from the hydro-chloric acid, producing > water and free chlorine. The free chlorine recombines with copper > from the board and produces copper-chloride. There's more to it, but > I'm not going to reprint it here. There's a lot of great technical > details on previous posts and in the links section. Do note though > that acid from the hardware store is about 30% to start with and > various H2O2 supplies are different percentages too. > > > -Denny
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Re: [Homebrew_PCBs] Re: Etching - thoughts and a respect for chemicals.
2004-01-17 by Tony Harris
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