Copper (II) Chloride Etchant
2010-04-04 by Chris Maness
I learned something new today. This is the second time I used CuCl2 to etch circuit boards. The first time it was a fresh batch of 15% HCl + 3% H202 in a 1:1 ratio. This worked very well. I brought out the same batch again several weeks later. Since, it was stored in a clear container, all of the H2O2 was gone due to light exposure. I didn't think it was a problem since there was no brown CuCl present. However, what I did not know is that the board builds up a layer of CuCl over the board. This layer is insoluble and prevents the board from etching further. It sat in the tank for almost the whole day because I could not find my H2O2, and it was just a scratch test anyhow. It still had not etched. I finally found my peroxide. I tossed a little in and it finished in 5 minutes. So I guess one needs a shot of peroxide if an aerator is not used. One would guess that it would need to be evaporated to keep the solution strong if one was adding peroxide every time. Too bad that I couldn't add Cu (II) Perchlorate or something to keep the Cu+ oxidized to Cu++. This would keep the solution from getting dilute. Chris KQ6UP [Non-text portions of this message have been removed]