Digital BW, The Print

Ok, I'm a newbie to this group.

I am interested in where to start to begin printing B&W.  Can anybody 
point me in the right direction?  I shoot a Canon 5D.  I print with an 
Epson 2200.  I use Photoshop CS.  What's the starting workflow?  
Thanks for any help you can give in pointing me in the best starting 
direction.  Is there a primer on the subject I can buy or read on the 
web?  Thanks.

Steve Holderfield