Thanks for the chemistry lesson. I think I'll give the sodium carbonate a try if this checks out. As I recall from my homebrew photo developer days, regular grocery-store "washing soda" (not baking soda) is sodium carbonate (monohydrated). It's cheap and very easy to get! How well would this work? Also, 200 degrees C is about 390F, so if all that outgases from heating the remaining precipitate is CO2, is there any reason I couldn't use my kitchen oven? Or . . . the toaster over I've dedicated for surface-mount reflow soldering? 73, Todd ------------------------------------------------------------------------------------ K7TFC / Medford, Oregon, USA / CN82ni / UTC-8 ------------------------------------------------------------------------------------ QRP (CW & SSB) / EmComm / SOTA / Homebrew / Design On Tue, Mar 12, 2013 at 10:32 AM, smilingcat90254 <smilingcat@...>wrote: > ** > > > Easiest disposal of CuCl2 solution. > > Since you don't know how much HCl is left in the solution, the best thing > to do is to use Sodium carbonate. It can be easily obtained from a pottery > supply stores. Cheap. Ask a high school ceramic instructor on where to get > it or ask any self respecting potter or ceramics artist. Cost is around > $2-$4 per pound I think... You don't need much more than a pound for a very > long time. > > Pour sodium carbonate crystals into your "spent" solution. Excess sodium > carbonate is fine. CuCl2 will react and precipitate out as Copper > carbonate. Filter it out using coffee filter. Liquid should be excess > sodium carbonate, regular table salt and water. > > Dump the liquid down a drain. > > Dump the Copper carbonate precipitate into trash. > > If you really want to be safe!! You can reduce the copper carbonate in a > furnace/kiln and heat the copper carbonate to around 200C. And it will turn > black. You are decomposing the carbonate to release CO2 and what remains is > Copper oxide. black powder. At this point its, very safe. But it can stain > clothing. > > Dumping Copper chloride solution into a bucket of wood chips makes more > toxic waste, so stop it!! > > Follow the directions on this post and all is well. > > BTW, same procedure works for Ferric Chloride etchant. If it is used on > Ferric chloride solution, I would decompose the precipitate in a furnace. > to create iron oxide, (rust). > > > [Non-text portions of this message have been removed]
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Re: [Homebrew_PCBs] Re: trying to do the right thing
2013-03-12 by Todd F. Carney / K7TFC
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