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Glossy Carbon Inks

Glossy Carbon Inks

2010-04-07 by ben

I am wondering what carbon based inks are available for printing on glossy stocks like Epson's Exhibition Glossy paper?

I have converted a R1800 to a 3K photo black printer using OEM inks.  The prints are nice except for a slight bronzing.  The bronzing is greatly reduced by waxing.

I would like to find a good B&W carbon based ink set which will work well on a glossy surface.  Since my R1800s are getting old, I would be up to purchasing a new printer.

Ben

Re: [Digital BW] Glossy Carbon Inks

2010-04-07 by Mark Savoia

Try spraying them with Lumijet.

Mark
http://www.stillrivereditions.com
Show quoted textHide quoted text
On Apr 7, 2010, at 8:43 AM, ben wrote:

> I am wondering what carbon based inks are available for printing on  
> glossy stocks like Epson's Exhibition Glossy paper?
>
> I have converted a R1800 to a 3K photo black printer using OEM  
> inks.  The prints are nice except for a slight bronzing.  The  
> bronzing is greatly reduced by waxing.
>
> I would like to find a good B&W carbon based ink set which will work  
> well on a glossy surface.  Since my R1800s are getting old, I would  
> be up to purchasing a new printer.
>
> Ben

Re: Glossy Carbon Inks

2010-04-07 by piezobw

Ben,

You might try overprinting with Piezography Gloss Optimizer which is a polyester material - if you can spare a channel on your printer for that purpose. We can supply you with a QTR curve to control it if you have a means by which to supply the GO into the printer. The refillable carts and CIS systems we sell require an entire set of chips in order to function - so they won't work with the OEM carts in place.

But, my GO would eliminate the bronzing and may potentially remove any gloss differential between ink and paper. It removes all gloss differential with Piezography glossy inks - but I do not know if it would function in the same way with Epson 3K blacks. Both inks are encapsulated - and the potential is good for the solution to work in the same way.

Mark's suggestion of spraying with Lumijet will also work if you do not mind the spraying. Many of my Piezography glossy customers spray because they do not have enough ink channels to run a GO with the six or seven shades of Piezography glossy ink.

As far as Carbon glossy inks - we sell so little of our Warm Neutral Glossy inks in comparison to the Selenium glossy inks. Going even further warmer would not seem to attract enough customers to warrant a production of triple encapsulated carbon (which is how we go glossy). However, it may be possible that I will use triple encapsulation on all my inks later in 2010 to make everything matte/glossy compatible. Right now just Selenium K7 and Warm Neutral K7 have this treatment and it does not affect its ability on matte. It just adds additional expense to the making of the ink. So - keep attention to my website or sign up for the newsletters here:

http://shopping.netsuite.com/s.nl/c.362672/it.I/id.217/.f

Jon Cone



--- In DigitalBlackandWhiteThePrint@yahoogroups.com, "ben" <benjschneider2@...> wrote:
Show quoted textHide quoted text
>
> I am wondering what carbon based inks are available for printing on glossy stocks like Epson's Exhibition Glossy paper?
> 
> I have converted a R1800 to a 3K photo black printer using OEM inks.  The prints are nice except for a slight bronzing.  The bronzing is greatly reduced by waxing.
> 
> I would like to find a good B&W carbon based ink set which will work well on a glossy surface.  Since my R1800s are getting old, I would be up to purchasing a new printer.
> 
> Ben
>

Re: Glossy Carbon Inks

2010-04-07 by pr_roark

"ben" <benjschneider2@...> wrote:
>
> I am wondering what carbon based inks are available for printing on glossy stocks like Epson's Exhibition Glossy paper?  ...

The MIS K4 LLK, LK, PK, and various UT inks (e.g., UT7 C and LC) are 100% carbon and glossy compatible.  They are very warm on glossy paper, with a Lab B = 14 (plus or minus a little).  This puts them into what I consider a light sepia range.

The best glossy neutralized gray ink is HP's Z3100/3200 PK, LK ("gray"), & LLK ("light gray").  Since the HP inks are coated, the light ones can be user-diluted with the generic base <http://www.paulroark.com/BW-Info/Ink-Mixing.pdf> and still be glossy compatible.  They can be diluted with MIS glop or a mix of 50% glop and C6 base, and the ink will then have less bronzing than the OEM mix.  Glop or a spray can, of course, reduce the bronzing.

In general, the MIS approach -- having the coating in the base and not on the particle -- appears to reduce bronzing, but it also results in a slightly less glossy appearance.  I like this, but it means the super-high gloss look can't really be achieved with the MIS inks without a post-printing spray.  

It also means that the MIS glossy dmax is a bit less than the coated PKs can achieve.  (Some say the super high dmax glossy PKs also have dye in them.  That could also be why the MIS carbon PK is a bit lower in dmax.  I don't know about that.)  At any rate, I use the HP PK for the glossy K even with the MIS LK when I want a sepia in my 1400.  The neutral HP PK does not significantly affect the sepia tone.  In my 7800, I'm going with MIS PK because I do want 100% carbon in that printer.

The warm MIS and neutral-cool HP inks can be in separate channels to make a variable tone inkset.  My 1400 is now set up with MIS LK and HP PK, allowing me to print from sepia to neutral-cool on glossy paper. 

The only 100% carbon print I've been able to make that is neutral required spraying Eboni, which had to be applied in a black only mode.  So, it was a bit rough and a hassle to make.  I don't recommend it.

Hope this helps.

Paul
www.PaulRoark.com

Re: Glossy Carbon Inks

2010-04-07 by shileshjani

Paul,

Thank you for the information below. I did not know that K4 (presumably Image Specialist) LK and LLK were 100% carbon. I thought 100% carbon inks (e.g. Cone Sepia) were not gloss compatible. I can indeed attest that these MIS K4 are significantly warmer than equivalent Epson OEM K3 inks.

So:

(1) Are OEM LK and LLK not 100% carbon?
(2) Are Cone Color K3 compatible LK and LLK also not 100% carbon because they purport to mimick the OEM colors?
(3) Is there any fade data available for K4 PK, LK, and LLK used without color inks?

Also, what is the significance of "triple encapsulation" that is used for Cone inks? As distinct from "resinated" inks used by Image Specialist?

I personally find the color of K4 LK and LLK (warm/red) to be gorgeous compared to OEM equivalents, which seem warm/green.

Shilesh

--- In DigitalBlackandWhiteThePrint@yahoogroups.com, "pr_roark" <roark.paul@...> wrote:
Show quoted textHide quoted text
>
> "ben" <benjschneider2@> wrote:
> >
> > I am wondering what carbon based inks are available for printing on glossy stocks like Epson's Exhibition Glossy paper?  ...
> 
> The MIS K4 LLK, LK, PK, and various UT inks (e.g., UT7 C and LC) are 100% carbon and glossy compatible.  They are very warm on glossy paper, with a Lab B = 14 (plus or minus a little).  This puts them into what I consider a light sepia range.
> 
> The best glossy neutralized gray ink is HP's Z3100/3200 PK, LK ("gray"), & LLK ("light gray").  Since the HP inks are coated, the light ones can be user-diluted with the generic base <http://www.paulroark.com/BW-Info/Ink-Mixing.pdf> and still be glossy compatible.  They can be diluted with MIS glop or a mix of 50% glop and C6 base, and the ink will then have less bronzing than the OEM mix.  Glop or a spray can, of course, reduce the bronzing.
> 
> In general, the MIS approach -- having the coating in the base and not on the particle -- appears to reduce bronzing, but it also results in a slightly less glossy appearance.  I like this, but it means the super-high gloss look can't really be achieved with the MIS inks without a post-printing spray.  
> 
> It also means that the MIS glossy dmax is a bit less than the coated PKs can achieve.  (Some say the super high dmax glossy PKs also have dye in them.  That could also be why the MIS carbon PK is a bit lower in dmax.  I don't know about that.)  At any rate, I use the HP PK for the glossy K even with the MIS LK when I want a sepia in my 1400.  The neutral HP PK does not significantly affect the sepia tone.  In my 7800, I'm going with MIS PK because I do want 100% carbon in that printer.
> 
> The warm MIS and neutral-cool HP inks can be in separate channels to make a variable tone inkset.  My 1400 is now set up with MIS LK and HP PK, allowing me to print from sepia to neutral-cool on glossy paper. 
> 
> The only 100% carbon print I've been able to make that is neutral required spraying Eboni, which had to be applied in a black only mode.  So, it was a bit rough and a hassle to make.  I don't recommend it.
> 
> Hope this helps.
> 
> Paul
> www.PaulRoark.com
>

Re: Glossy Carbon Inks

2010-04-07 by piezobw

Shilesh,

Encapsulation is an expensive and wasteful process that is difficult and it's not something that many companies can attempt. Epson and HP do. HP probably has the best encapsulation process because it also negatively charges the resin layer which aids keeping pigment in suspension. 

Piezography started doing encapsulation in 2005 for one specific reason: pigment particles have static charges. The charges attract one another and this attraction causes pigment particles to agglomerate and form tiny clumps. Even tiny clumps of several hundred pigment particles can clog a print head. Encapsulation in a polyester micro-coating that completely seals the pigment particle and eliminates the ability of a pigment particle to attract another pigment particle. We started this with K7 and this ink has proven to be very clog free as a result.

Resin is used to produce better gloss adhesion in an ink vehicle. But polyester encapsulation will also produce the same effect when the encapsulation is thick enough. Because encapsulation only produces an extremely thin layer, it takes a triple process in order to produce a thick enough coating to promote glossiness - hence the triple encapsulation.

Resin can act to absorb some electrical charges, but can not eliminate them. It's considered the poor man's encapsulation. MediaStreet inks were one of the most popular examples of resinated inks before they closed. Resinating is literally a physical process of mixing a dispersion into a base that is high in resin and usually occurs as a last stage in the ink making process. Encapsulation takes place during the pigment modification stages and well before the ink making stages.

The difference between the two processes is a hard thing for many to picture in their mind. I am getting some time on an electron-microscope and I hope to be able to post images soon of the differences in PiezoTone Sepia pigment particles and Piezography K7 pigment particles. The challenge of course is with imaging these materials. We recently produced a portfolio of images for a scientist working with an electron-microscope and who has access to two different technologies. When we get images we will post them and show them. We are hopeful that the coating will be apparent and make visual sense.  Otherwise - bite into an M&M candy carefully so that you leave the hard candy outer shell intact along with the soft chocolate center. That is a perfect cross-section example of encapsulation and easy to picture in your mind.


The ConeColor LKs do not try and improve on the OEM. So I carefully replicated the greenish/brownish cast of the OEM. To improve things you can replace the OEM shades LK with a Piezography shade #4 and OEM LLK with a Piezography shade #5.

Jon Cone

--- In DigitalBlackandWhiteThePrint@yahoogroups.com, "shileshjani" <janishilesh@...> wrote:
Show quoted textHide quoted text
>
> Paul,
> 
> Thank you for the information below. I did not know that K4 (presumably Image Specialist) LK and LLK were 100% carbon. I thought 100% carbon inks (e.g. Cone Sepia) were not gloss compatible. I can indeed attest that these MIS K4 are significantly warmer than equivalent Epson OEM K3 inks.
> 
> So:
> 
> (1) Are OEM LK and LLK not 100% carbon?
> (2) Are Cone Color K3 compatible LK and LLK also not 100% carbon because they purport to mimick the OEM colors?
> (3) Is there any fade data available for K4 PK, LK, and LLK used without color inks?
> 
> Also, what is the significance of "triple encapsulation" that is used for Cone inks? As distinct from "resinated" inks used by Image Specialist?
> 
> I personally find the color of K4 LK and LLK (warm/red) to be gorgeous compared to OEM equivalents, which seem warm/green.
> 
> Shilesh
> 
> --- In DigitalBlackandWhiteThePrint@yahoogroups.com, "pr_roark" <roark.paul@> wrote:
> >
> > "ben" <benjschneider2@> wrote:
> > >
> > > I am wondering what carbon based inks are available for printing on glossy stocks like Epson's Exhibition Glossy paper?  ...
> > 
> > The MIS K4 LLK, LK, PK, and various UT inks (e.g., UT7 C and LC) are 100% carbon and glossy compatible.  They are very warm on glossy paper, with a Lab B = 14 (plus or minus a little).  This puts them into what I consider a light sepia range.
> > 
> > The best glossy neutralized gray ink is HP's Z3100/3200 PK, LK ("gray"), & LLK ("light gray").  Since the HP inks are coated, the light ones can be user-diluted with the generic base <http://www.paulroark.com/BW-Info/Ink-Mixing.pdf> and still be glossy compatible.  They can be diluted with MIS glop or a mix of 50% glop and C6 base, and the ink will then have less bronzing than the OEM mix.  Glop or a spray can, of course, reduce the bronzing.
> > 
> > In general, the MIS approach -- having the coating in the base and not on the particle -- appears to reduce bronzing, but it also results in a slightly less glossy appearance.  I like this, but it means the super-high gloss look can't really be achieved with the MIS inks without a post-printing spray.  
> > 
> > It also means that the MIS glossy dmax is a bit less than the coated PKs can achieve.  (Some say the super high dmax glossy PKs also have dye in them.  That could also be why the MIS carbon PK is a bit lower in dmax.  I don't know about that.)  At any rate, I use the HP PK for the glossy K even with the MIS LK when I want a sepia in my 1400.  The neutral HP PK does not significantly affect the sepia tone.  In my 7800, I'm going with MIS PK because I do want 100% carbon in that printer.
> > 
> > The warm MIS and neutral-cool HP inks can be in separate channels to make a variable tone inkset.  My 1400 is now set up with MIS LK and HP PK, allowing me to print from sepia to neutral-cool on glossy paper. 
> > 
> > The only 100% carbon print I've been able to make that is neutral required spraying Eboni, which had to be applied in a black only mode.  So, it was a bit rough and a hassle to make.  I don't recommend it.
> > 
> > Hope this helps.
> > 
> > Paul
> > www.PaulRoark.com
> >
>

Re: [Digital BW] Re: Glossy Carbon Inks

2010-04-07 by Mark Savoia

Hey, they are all sepia inside, ...who knew?

Mark
http://www.stillrivereditions.com
Show quoted textHide quoted text
On Apr 7, 2010, at 3:18 PM, piezobw wrote:

> Otherwise - bite into an M&M candy carefully so that you leave the  
> hard candy outer shell intact along with the soft chocolate center.  
> That is a perfect cross-section example of encapsulation and easy to  
> picture in your mind.

[Digital BW] Re: Glossy Carbon Inks

2010-04-07 by piezobw

:)  ...i miss milk chocolate

I'm lactose intolerant and they actually add lactose to m&ms - I always thought that that might be the thin white layer between the chocolate and the hard candy shell...

Jon Cone

--- In DigitalBlackandWhiteThePrint@yahoogroups.com, Mark Savoia <mark@...> wrote:
Show quoted textHide quoted text
>
> Hey, they are all sepia inside, ...who knew?
> 
> Mark
> http://www.stillrivereditions.com
> 
> On Apr 7, 2010, at 3:18 PM, piezobw wrote:
> 
> > Otherwise - bite into an M&M candy carefully so that you leave the  
> > hard candy outer shell intact along with the soft chocolate center.  
> > That is a perfect cross-section example of encapsulation and easy to  
> > picture in your mind.
>

Re: [Digital BW] Re: Glossy Carbon Inks

2010-04-07 by Bruce Watson

piezobw wrote:
> :)  ...i miss milk chocolate
>
> I'm lactose intolerant and they actually add lactose to m&ms - I always thought that that might be the thin white layer between the chocolate and the hard candy shell...
>
> Jon Cone
I miss M&Ms too. I gave 'em up because of the color dyes. I don't mind 
printing with them, but there seems to be a fair amount of doubt about 
their being harmless to human health. So why chance it? Just like BPA 
from plastic water bottles. And soy products, and...

Oh, damn. Never mind. Someone hit my "rant" switch. It's back off. For 
now. ;-)
--
Bruce Watson

Re: Glossy Carbon Inks

2010-04-07 by shileshjani

OK. I get the difference between resinated and encapsulated. I doubt you will see much meaningful differences on an electron microscope (other than size), especially a scanning electron microscope operating at high EV. On a transimission electron microscope - potentially, yes. But how do you slice the proverbial sub-micron encapsulated pigment M&M? I drive electron microscopes at work, so I am eager to see your results.

OK, so are OEM LK and LLK not 100% carbon? And ConeColor LK and LLK?

Shilesh
--- In DigitalBlackandWhiteThePrint@yahoogroups.com, "piezobw" <jon@...> wrote:
Show quoted textHide quoted text
>
> Shilesh,
> 
> Encapsulation is an expensive and wasteful process that is difficult and it's not something that many companies can attempt. Epson and HP do. HP probably has the best encapsulation process because it also negatively charges the resin layer which aids keeping pigment in suspension. 
> 
> Piezography started doing encapsulation in 2005 for one specific reason: pigment particles have static charges. The charges attract one another and this attraction causes pigment particles to agglomerate and form tiny clumps. Even tiny clumps of several hundred pigment particles can clog a print head. Encapsulation in a polyester micro-coating that completely seals the pigment particle and eliminates the ability of a pigment particle to attract another pigment particle. We started this with K7 and this ink has proven to be very clog free as a result.
> 
> Resin is used to produce better gloss adhesion in an ink vehicle. But polyester encapsulation will also produce the same effect when the encapsulation is thick enough. Because encapsulation only produces an extremely thin layer, it takes a triple process in order to produce a thick enough coating to promote glossiness - hence the triple encapsulation.
> 
> Resin can act to absorb some electrical charges, but can not eliminate them. It's considered the poor man's encapsulation. MediaStreet inks were one of the most popular examples of resinated inks before they closed. Resinating is literally a physical process of mixing a dispersion into a base that is high in resin and usually occurs as a last stage in the ink making process. Encapsulation takes place during the pigment modification stages and well before the ink making stages.
> 
> The difference between the two processes is a hard thing for many to picture in their mind. I am getting some time on an electron-microscope and I hope to be able to post images soon of the differences in PiezoTone Sepia pigment particles and Piezography K7 pigment particles. The challenge of course is with imaging these materials. We recently produced a portfolio of images for a scientist working with an electron-microscope and who has access to two different technologies. When we get images we will post them and show them. We are hopeful that the coating will be apparent and make visual sense.  Otherwise - bite into an M&M candy carefully so that you leave the hard candy outer shell intact along with the soft chocolate center. That is a perfect cross-section example of encapsulation and easy to picture in your mind.
> 
> 
> The ConeColor LKs do not try and improve on the OEM. So I carefully replicated the greenish/brownish cast of the OEM. To improve things you can replace the OEM shades LK with a Piezography shade #4 and OEM LLK with a Piezography shade #5.
> 
> Jon Cone
> 
> --- In DigitalBlackandWhiteThePrint@yahoogroups.com, "shileshjani" <janishilesh@> wrote:
> >
> > Paul,
> > 
> > Thank you for the information below. I did not know that K4 (presumably Image Specialist) LK and LLK were 100% carbon. I thought 100% carbon inks (e.g. Cone Sepia) were not gloss compatible. I can indeed attest that these MIS K4 are significantly warmer than equivalent Epson OEM K3 inks.
> > 
> > So:
> > 
> > (1) Are OEM LK and LLK not 100% carbon?
> > (2) Are Cone Color K3 compatible LK and LLK also not 100% carbon because they purport to mimick the OEM colors?
> > (3) Is there any fade data available for K4 PK, LK, and LLK used without color inks?
> > 
> > Also, what is the significance of "triple encapsulation" that is used for Cone inks? As distinct from "resinated" inks used by Image Specialist?
> > 
> > I personally find the color of K4 LK and LLK (warm/red) to be gorgeous compared to OEM equivalents, which seem warm/green.
> > 
> > Shilesh
> > 
> > --- In DigitalBlackandWhiteThePrint@yahoogroups.com, "pr_roark" <roark.paul@> wrote:
> > >
> > > "ben" <benjschneider2@> wrote:
> > > >
> > > > I am wondering what carbon based inks are available for printing on glossy stocks like Epson's Exhibition Glossy paper?  ...
> > > 
> > > The MIS K4 LLK, LK, PK, and various UT inks (e.g., UT7 C and LC) are 100% carbon and glossy compatible.  They are very warm on glossy paper, with a Lab B = 14 (plus or minus a little).  This puts them into what I consider a light sepia range.
> > > 
> > > The best glossy neutralized gray ink is HP's Z3100/3200 PK, LK ("gray"), & LLK ("light gray").  Since the HP inks are coated, the light ones can be user-diluted with the generic base <http://www.paulroark.com/BW-Info/Ink-Mixing.pdf> and still be glossy compatible.  They can be diluted with MIS glop or a mix of 50% glop and C6 base, and the ink will then have less bronzing than the OEM mix.  Glop or a spray can, of course, reduce the bronzing.
> > > 
> > > In general, the MIS approach -- having the coating in the base and not on the particle -- appears to reduce bronzing, but it also results in a slightly less glossy appearance.  I like this, but it means the super-high gloss look can't really be achieved with the MIS inks without a post-printing spray.  
> > > 
> > > It also means that the MIS glossy dmax is a bit less than the coated PKs can achieve.  (Some say the super high dmax glossy PKs also have dye in them.  That could also be why the MIS carbon PK is a bit lower in dmax.  I don't know about that.)  At any rate, I use the HP PK for the glossy K even with the MIS LK when I want a sepia in my 1400.  The neutral HP PK does not significantly affect the sepia tone.  In my 7800, I'm going with MIS PK because I do want 100% carbon in that printer.
> > > 
> > > The warm MIS and neutral-cool HP inks can be in separate channels to make a variable tone inkset.  My 1400 is now set up with MIS LK and HP PK, allowing me to print from sepia to neutral-cool on glossy paper. 
> > > 
> > > The only 100% carbon print I've been able to make that is neutral required spraying Eboni, which had to be applied in a black only mode.  So, it was a bit rough and a hassle to make.  I don't recommend it.
> > > 
> > > Hope this helps.
> > > 
> > > Paul
> > > www.PaulRoark.com
> > >
> >
>

Re: [Digital BW] Black, as in Chocolate...

2010-04-07 by C D Tobie

Its not just  the candy and colorings on the outside of M&Ms, its the  
lack of good chocolate on the inside. On a B&W list, I have to assume  
proper black chocolate is preferred. I like mine with espresso beans  
or a bit of cayenne pepper in it (I can recall Jon salvaging my  
adrenal system with dark chocolate espresso beans at the end of a long  
show). Those additions don't seem to effect the D-max too much.  
Lindt's factory isn't all that far from our offices in Zurich...

On Apr 7, 2010, at 3:47 PM, Bruce Watson wrote:

> piezobw wrote:
>> :)  ...i miss milk chocolate
>>
>> I'm lactose intolerant and they actually add lactose to m&ms - I  
>> always thought that that might be the thin white layer between the  
>> chocolate and the hard candy shell...
>>
>> Jon Cone
> I miss M&Ms too. I gave 'em up because of the color dyes. I don't mind
> printing with them, but there seems to be a fair amount of doubt about
> their being harmless to human health. So why chance it? Just like BPA
> from plastic water bottles. And soy products, and...

C. David Tobie
Global Product Technology Manager
Digital Imaging & Home Theater
CDTobie@...
Datacolor
www.datacolor.com/Spyder3

Re: Glossy Carbon Inks

2010-04-07 by piezobw

Shilesh,

I wonder if the two pigment particles (unocated and coated) will show up differently?  They are not going to be sliced - but rather imaged as dry powder particles. I haven't seen pigment imaged before at this level - but I would anticipate one will be rough, the other smoother? Will be a disappointment if they're too tiny or the material inside or outside causes imaging problems (which is what she is anticipating and is considering using a second type of technology in anticipation.) She has imaged carbon nano-tubes successfully. Those I saw.

ConeColor LK and LLK are not pure carbon - you could substitute Sepia K7 shades #4 and #5 for the pure carbon affect. We have a number of customers now running Piezography shades #1, #4, #5 in several flavors in their ABW systems.

My understanding from reading the HP patents is that they do not permit a range of shades from a competitor such as Epson to produce "neutral" oriented lt blacks. Epson has to remain outside a very specific range of ab that they published as "their invention" - which of course is debatable were it further examined. Anways, that was my read on it but I'm not the lawyer.

Jon Cone




--- In DigitalBlackandWhiteThePrint@yahoogroups.com, "shileshjani" <janishilesh@...> wrote:
Show quoted textHide quoted text
>
> OK. I get the difference between resinated and encapsulated. I doubt you will see much meaningful differences on an electron microscope (other than size), especially a scanning electron microscope operating at high EV. On a transimission electron microscope - potentially, yes. But how do you slice the proverbial sub-micron encapsulated pigment M&M? I drive electron microscopes at work, so I am eager to see your results.
> 
> OK, so are OEM LK and LLK not 100% carbon? And ConeColor LK and LLK?
> 
> Shilesh
> --- In DigitalBlackandWhiteThePrint@yahoogroups.com, "piezobw" <jon@> wrote:
> >
> > Shilesh,
> > 
> > Encapsulation is an expensive and wasteful process that is difficult and it's not something that many companies can attempt. Epson and HP do. HP probably has the best encapsulation process because it also negatively charges the resin layer which aids keeping pigment in suspension. 
> > 
> > Piezography started doing encapsulation in 2005 for one specific reason: pigment particles have static charges. The charges attract one another and this attraction causes pigment particles to agglomerate and form tiny clumps. Even tiny clumps of several hundred pigment particles can clog a print head. Encapsulation in a polyester micro-coating that completely seals the pigment particle and eliminates the ability of a pigment particle to attract another pigment particle. We started this with K7 and this ink has proven to be very clog free as a result.
> > 
> > Resin is used to produce better gloss adhesion in an ink vehicle. But polyester encapsulation will also produce the same effect when the encapsulation is thick enough. Because encapsulation only produces an extremely thin layer, it takes a triple process in order to produce a thick enough coating to promote glossiness - hence the triple encapsulation.
> > 
> > Resin can act to absorb some electrical charges, but can not eliminate them. It's considered the poor man's encapsulation. MediaStreet inks were one of the most popular examples of resinated inks before they closed. Resinating is literally a physical process of mixing a dispersion into a base that is high in resin and usually occurs as a last stage in the ink making process. Encapsulation takes place during the pigment modification stages and well before the ink making stages.
> > 
> > The difference between the two processes is a hard thing for many to picture in their mind. I am getting some time on an electron-microscope and I hope to be able to post images soon of the differences in PiezoTone Sepia pigment particles and Piezography K7 pigment particles. The challenge of course is with imaging these materials. We recently produced a portfolio of images for a scientist working with an electron-microscope and who has access to two different technologies. When we get images we will post them and show them. We are hopeful that the coating will be apparent and make visual sense.  Otherwise - bite into an M&M candy carefully so that you leave the hard candy outer shell intact along with the soft chocolate center. That is a perfect cross-section example of encapsulation and easy to picture in your mind.
> > 
> > 
> > The ConeColor LKs do not try and improve on the OEM. So I carefully replicated the greenish/brownish cast of the OEM. To improve things you can replace the OEM shades LK with a Piezography shade #4 and OEM LLK with a Piezography shade #5.
> > 
> > Jon Cone
> > 
> > --- In DigitalBlackandWhiteThePrint@yahoogroups.com, "shileshjani" <janishilesh@> wrote:
> > >
> > > Paul,
> > > 
> > > Thank you for the information below. I did not know that K4 (presumably Image Specialist) LK and LLK were 100% carbon. I thought 100% carbon inks (e.g. Cone Sepia) were not gloss compatible. I can indeed attest that these MIS K4 are significantly warmer than equivalent Epson OEM K3 inks.
> > > 
> > > So:
> > > 
> > > (1) Are OEM LK and LLK not 100% carbon?
> > > (2) Are Cone Color K3 compatible LK and LLK also not 100% carbon because they purport to mimick the OEM colors?
> > > (3) Is there any fade data available for K4 PK, LK, and LLK used without color inks?
> > > 
> > > Also, what is the significance of "triple encapsulation" that is used for Cone inks? As distinct from "resinated" inks used by Image Specialist?
> > > 
> > > I personally find the color of K4 LK and LLK (warm/red) to be gorgeous compared to OEM equivalents, which seem warm/green.
> > > 
> > > Shilesh
> > > 
> > > --- In DigitalBlackandWhiteThePrint@yahoogroups.com, "pr_roark" <roark.paul@> wrote:
> > > >
> > > > "ben" <benjschneider2@> wrote:
> > > > >
> > > > > I am wondering what carbon based inks are available for printing on glossy stocks like Epson's Exhibition Glossy paper?  ...
> > > > 
> > > > The MIS K4 LLK, LK, PK, and various UT inks (e.g., UT7 C and LC) are 100% carbon and glossy compatible.  They are very warm on glossy paper, with a Lab B = 14 (plus or minus a little).  This puts them into what I consider a light sepia range.
> > > > 
> > > > The best glossy neutralized gray ink is HP's Z3100/3200 PK, LK ("gray"), & LLK ("light gray").  Since the HP inks are coated, the light ones can be user-diluted with the generic base <http://www.paulroark.com/BW-Info/Ink-Mixing.pdf> and still be glossy compatible.  They can be diluted with MIS glop or a mix of 50% glop and C6 base, and the ink will then have less bronzing than the OEM mix.  Glop or a spray can, of course, reduce the bronzing.
> > > > 
> > > > In general, the MIS approach -- having the coating in the base and not on the particle -- appears to reduce bronzing, but it also results in a slightly less glossy appearance.  I like this, but it means the super-high gloss look can't really be achieved with the MIS inks without a post-printing spray.  
> > > > 
> > > > It also means that the MIS glossy dmax is a bit less than the coated PKs can achieve.  (Some say the super high dmax glossy PKs also have dye in them.  That could also be why the MIS carbon PK is a bit lower in dmax.  I don't know about that.)  At any rate, I use the HP PK for the glossy K even with the MIS LK when I want a sepia in my 1400.  The neutral HP PK does not significantly affect the sepia tone.  In my 7800, I'm going with MIS PK because I do want 100% carbon in that printer.
> > > > 
> > > > The warm MIS and neutral-cool HP inks can be in separate channels to make a variable tone inkset.  My 1400 is now set up with MIS LK and HP PK, allowing me to print from sepia to neutral-cool on glossy paper. 
> > > > 
> > > > The only 100% carbon print I've been able to make that is neutral required spraying Eboni, which had to be applied in a black only mode.  So, it was a bit rough and a hassle to make.  I don't recommend it.
> > > > 
> > > > Hope this helps.
> > > > 
> > > > Paul
> > > > www.PaulRoark.com
> > > >
> > >
> >
>

Re: [Digital BW] Black, as in Chocolate...

2010-04-07 by piezobw

David, 

We have had some memorable moments... I remember that. By the way, if you come visit us in Vermont, we keep two automated espresso machines always on the nearby, plugged in and ready 24/7 - and I'm totally into high percentage cocoa chocolates these days. We can dip the 85% into rich espresso for nearly the same affect.

Jon Cone

--- In DigitalBlackandWhiteThePrint@yahoogroups.com, C D Tobie <CDTobie@...> wrote:
Show quoted textHide quoted text
>
> Its not just  the candy and colorings on the outside of M&Ms, its the  
> lack of good chocolate on the inside. On a B&W list, I have to assume  
> proper black chocolate is preferred. I like mine with espresso beans  
> or a bit of cayenne pepper in it (I can recall Jon salvaging my  
> adrenal system with dark chocolate espresso beans at the end of a long  
> show). Those additions don't seem to effect the D-max too much.  
> Lindt's factory isn't all that far from our offices in Zurich...
> 
> On Apr 7, 2010, at 3:47 PM, Bruce Watson wrote:
> 
> > piezobw wrote:
> >> :)  ...i miss milk chocolate
> >>
> >> I'm lactose intolerant and they actually add lactose to m&ms - I  
> >> always thought that that might be the thin white layer between the  
> >> chocolate and the hard candy shell...
> >>
> >> Jon Cone
> > I miss M&Ms too. I gave 'em up because of the color dyes. I don't mind
> > printing with them, but there seems to be a fair amount of doubt about
> > their being harmless to human health. So why chance it? Just like BPA
> > from plastic water bottles. And soy products, and...
> 
> C. David Tobie
> Global Product Technology Manager
> Digital Imaging & Home Theater
> CDTobie@...
> Datacolor
> www.datacolor.com/Spyder3
>

Re: Glossy Carbon Inks

2010-04-07 by shileshjani

So if it is surfaces of pigments you are looking at, it would be scanning electron microscopy (SEM). If these particles are truly sub-micron (say 0.1 micron), then the expected roughness will be in range of nanometers. You are really pushing the resolution limit of an SEM. If your project uses what is known as a field emmision microscope, you may have some hope (not much in my estimation). These higher resolutions require higher accelearting voltage, which in turn causes greater penetration of electrons into your material, heating (even melting of polymers).

Transimission elctron microscope (TEM) is a better bet; you may be able to see the outer edge of the resin surrounding the pigment, but will not get much surface roughness information. See picture in the link below.

http://pubs.acs.org/doi/abs/10.1021/la7027466

Shilesh

PS: Maybe I need to spend some time in the EM lab with the veritable pools of inks I have at home. Sample prep would probably be a headache - I would rather someone else do it and show me the results.

--- In DigitalBlackandWhiteThePrint@yahoogroups.com, "piezobw" <jon@...> wrote:
Show quoted textHide quoted text
>
> Shilesh,
> 
> I wonder if the two pigment particles (unocated and coated) will show up differently?  They are not going to be sliced - but rather imaged as dry powder particles. I haven't seen pigment imaged before at this level - but I would anticipate one will be rough, the other smoother? Will be a disappointment if they're too tiny or the material inside or outside causes imaging problems (which is what she is anticipating and is considering using a second type of technology in anticipation.) She has imaged carbon nano-tubes successfully. Those I saw.
> 
> ConeColor LK and LLK are not pure carbon - you could substitute Sepia K7 shades #4 and #5 for the pure carbon affect. We have a number of customers now running Piezography shades #1, #4, #5 in several flavors in their ABW systems.
> 
> My understanding from reading the HP patents is that they do not permit a range of shades from a competitor such as Epson to produce "neutral" oriented lt blacks. Epson has to remain outside a very specific range of ab that they published as "their invention" - which of course is debatable were it further examined. Anways, that was my read on it but I'm not the lawyer.
> 
> Jon Cone
> 
> 
> 
> 
> --- In DigitalBlackandWhiteThePrint@yahoogroups.com, "shileshjani" <janishilesh@> wrote:
> >
> > OK. I get the difference between resinated and encapsulated. I doubt you will see much meaningful differences on an electron microscope (other than size), especially a scanning electron microscope operating at high EV. On a transimission electron microscope - potentially, yes. But how do you slice the proverbial sub-micron encapsulated pigment M&M? I drive electron microscopes at work, so I am eager to see your results.
> > 
> > OK, so are OEM LK and LLK not 100% carbon? And ConeColor LK and LLK?
> > 
> > Shilesh
> > --- In DigitalBlackandWhiteThePrint@yahoogroups.com, "piezobw" <jon@> wrote:
> > >
> > > Shilesh,
> > > 
> > > Encapsulation is an expensive and wasteful process that is difficult and it's not something that many companies can attempt. Epson and HP do. HP probably has the best encapsulation process because it also negatively charges the resin layer which aids keeping pigment in suspension. 
> > > 
> > > Piezography started doing encapsulation in 2005 for one specific reason: pigment particles have static charges. The charges attract one another and this attraction causes pigment particles to agglomerate and form tiny clumps. Even tiny clumps of several hundred pigment particles can clog a print head. Encapsulation in a polyester micro-coating that completely seals the pigment particle and eliminates the ability of a pigment particle to attract another pigment particle. We started this with K7 and this ink has proven to be very clog free as a result.
> > > 
> > > Resin is used to produce better gloss adhesion in an ink vehicle. But polyester encapsulation will also produce the same effect when the encapsulation is thick enough. Because encapsulation only produces an extremely thin layer, it takes a triple process in order to produce a thick enough coating to promote glossiness - hence the triple encapsulation.
> > > 
> > > Resin can act to absorb some electrical charges, but can not eliminate them. It's considered the poor man's encapsulation. MediaStreet inks were one of the most popular examples of resinated inks before they closed. Resinating is literally a physical process of mixing a dispersion into a base that is high in resin and usually occurs as a last stage in the ink making process. Encapsulation takes place during the pigment modification stages and well before the ink making stages.
> > > 
> > > The difference between the two processes is a hard thing for many to picture in their mind. I am getting some time on an electron-microscope and I hope to be able to post images soon of the differences in PiezoTone Sepia pigment particles and Piezography K7 pigment particles. The challenge of course is with imaging these materials. We recently produced a portfolio of images for a scientist working with an electron-microscope and who has access to two different technologies. When we get images we will post them and show them. We are hopeful that the coating will be apparent and make visual sense.  Otherwise - bite into an M&M candy carefully so that you leave the hard candy outer shell intact along with the soft chocolate center. That is a perfect cross-section example of encapsulation and easy to picture in your mind.
> > > 
> > > 
> > > The ConeColor LKs do not try and improve on the OEM. So I carefully replicated the greenish/brownish cast of the OEM. To improve things you can replace the OEM shades LK with a Piezography shade #4 and OEM LLK with a Piezography shade #5.
> > > 
> > > Jon Cone
> > > 
> > > --- In DigitalBlackandWhiteThePrint@yahoogroups.com, "shileshjani" <janishilesh@> wrote:
> > > >
> > > > Paul,
> > > > 
> > > > Thank you for the information below. I did not know that K4 (presumably Image Specialist) LK and LLK were 100% carbon. I thought 100% carbon inks (e.g. Cone Sepia) were not gloss compatible. I can indeed attest that these MIS K4 are significantly warmer than equivalent Epson OEM K3 inks.
> > > > 
> > > > So:
> > > > 
> > > > (1) Are OEM LK and LLK not 100% carbon?
> > > > (2) Are Cone Color K3 compatible LK and LLK also not 100% carbon because they purport to mimick the OEM colors?
> > > > (3) Is there any fade data available for K4 PK, LK, and LLK used without color inks?
> > > > 
> > > > Also, what is the significance of "triple encapsulation" that is used for Cone inks? As distinct from "resinated" inks used by Image Specialist?
> > > > 
> > > > I personally find the color of K4 LK and LLK (warm/red) to be gorgeous compared to OEM equivalents, which seem warm/green.
> > > > 
> > > > Shilesh
> > > > 
> > > > --- In DigitalBlackandWhiteThePrint@yahoogroups.com, "pr_roark" <roark.paul@> wrote:
> > > > >
> > > > > "ben" <benjschneider2@> wrote:
> > > > > >
> > > > > > I am wondering what carbon based inks are available for printing on glossy stocks like Epson's Exhibition Glossy paper?  ...
> > > > > 
> > > > > The MIS K4 LLK, LK, PK, and various UT inks (e.g., UT7 C and LC) are 100% carbon and glossy compatible.  They are very warm on glossy paper, with a Lab B = 14 (plus or minus a little).  This puts them into what I consider a light sepia range.
> > > > > 
> > > > > The best glossy neutralized gray ink is HP's Z3100/3200 PK, LK ("gray"), & LLK ("light gray").  Since the HP inks are coated, the light ones can be user-diluted with the generic base <http://www.paulroark.com/BW-Info/Ink-Mixing.pdf> and still be glossy compatible.  They can be diluted with MIS glop or a mix of 50% glop and C6 base, and the ink will then have less bronzing than the OEM mix.  Glop or a spray can, of course, reduce the bronzing.
> > > > > 
> > > > > In general, the MIS approach -- having the coating in the base and not on the particle -- appears to reduce bronzing, but it also results in a slightly less glossy appearance.  I like this, but it means the super-high gloss look can't really be achieved with the MIS inks without a post-printing spray.  
> > > > > 
> > > > > It also means that the MIS glossy dmax is a bit less than the coated PKs can achieve.  (Some say the super high dmax glossy PKs also have dye in them.  That could also be why the MIS carbon PK is a bit lower in dmax.  I don't know about that.)  At any rate, I use the HP PK for the glossy K even with the MIS LK when I want a sepia in my 1400.  The neutral HP PK does not significantly affect the sepia tone.  In my 7800, I'm going with MIS PK because I do want 100% carbon in that printer.
> > > > > 
> > > > > The warm MIS and neutral-cool HP inks can be in separate channels to make a variable tone inkset.  My 1400 is now set up with MIS LK and HP PK, allowing me to print from sepia to neutral-cool on glossy paper. 
> > > > > 
> > > > > The only 100% carbon print I've been able to make that is neutral required spraying Eboni, which had to be applied in a black only mode.  So, it was a bit rough and a hassle to make.  I don't recommend it.
> > > > > 
> > > > > Hope this helps.
> > > > > 
> > > > > Paul
> > > > > www.PaulRoark.com
> > > > >
> > > >
> > >
> >
>

Re: [Digital BW] Black, as in Chocolate...

2010-04-07 by Bruce Watson

C D Tobie wrote:
> Its not just  the candy and colorings on the outside of M&Ms, its the  
> lack of good chocolate on the inside. On a B&W list, I have to assume  
> proper black chocolate is preferred. 
I perhaps like mine a little more sepia than full black. And while I 
miss M&Ms a bit, I'm not feeling deprived in the least. Not when there's 
all those good chocolatiers in Europe, and excellent boutique 
chocolatiers in NA.

Wave a Lindt truffle at me and see how fast I drop that bag of M&Ms. 
Similarly to how I dropped color printing for Jon's PiezoTones a few 
years back. We B&W guys don't need no stinking color! ;-)
--
Bruce Watson

Re: Glossy Carbon Inks

2010-04-07 by pr_roark

"shileshjani" <janishilesh@...> wrote:

 
> ... I did not know that [MIS] K4 (presumably Image Specialist) LK and LLK were 100% carbon.

I've been told by MIS and IS they are, and in my tests they perform as I'd expect carbon to.  However, my tests are not as thorough as Mark's.

> ... these MIS K4 are significantly warmer than equivalent Epson OEM K3 inks.

And with the UT carbons like MIS UT7 C and LC, as well as EZ-W, you have a full set of different densities from PK to LLK:  K4-PK, UT7-C, K4-LK, EZ-W, UT7-LC, K4-LLK.

> (1) Are OEM LK and LLK not 100% carbon?

I don't know.  The K2 OEM PK nad LK tested very well for me -- like carbon.  They are less warm, perhaps due to larger particles.  They do not stay in suspension as well as the MIS warm carbons, which is also consistent with larger particle sizes.

...
> (3) Is there any fade data available for K4 PK, LK, and LLK used without color inks?

In addition to my testing, there is at least one Aardenburg Imaging test that had MIS PK in the black spot.  At that point it behaved consistently with what I'd expect from carbon.

> I personally find the color of K4 LK and LLK (warm/red) to be gorgeous compared to OEM equivalents, which seem warm/green.

The OEM K3 is un-usable by itself, in my view.


Paul
www.PaulRoark.com

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