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[Digital BW] Piezotone/Ultrachrome blacks was MIS inks - are they really pure pigment?

[Digital BW] Piezotone/Ultrachrome blacks was MIS inks - are they really pure pigment?

2002-10-04 by Paul Roark

Robert wrote:

>The rather disappointing thing about the matte black ultrachrome ink is how
>poor it performs (dmax) on every paper other than EAM.

I don't get it.  Epson comes up with some hot new technology that raises the
bar for image permanence and blackness for a black ink -- but only on a
paper that Wilhelm says has so much acid in it that it turns unacceptably
yellow in 30 years.  Don't the paper and ink departments at Epson talk to
each other?

Speaking of EAM, I tried some of that Bookkeeper deacidification spray on
the back of some.  (It's sold by Light Impressions.)  It, of course, made
the back of the EAM very basic. ("acid free"?)  The problem is that the
buffer does not penetrate very far into the paper.  I was hoping my vacuum
easel would pull it deeper, but it doesn't seem to make any difference.  (I
use an acid test pen on the edge of a cut piece of treated paper to see how
far the deacidification penetrated the paper.)

I'm going to see if the maker of the product has any information of how far
the H+ ions migrate.  Part of the theory and reason these treatments do, in
fact, work in many applications is that the H+ ions (which are what acids
have that cause the damage) do migrate, and the damage they do to the
cellulose is a slow reaction.  On the other hand, when the H+ ions reach a
buffer the reaction is very fast, and the ion is captured and put out of
business.  So, I assume there is a relationship between the distance the
ions typically travel, and penetration of the buffer, and the effectiveness
of the treatment.  Hopefully the maker has this data and will share it.

>  I'm still hoping
>that the new Somerset paper has a EAM like coating on it ...

That would be nice.  The Somerset I have used just doesn't have the
smoothness of EAM that I like so much.

> I just coated an Ultrachrome print on Museo today.  The dmax went
>from a very poor 1.48 to silver-like 2.13 as measured by my spectrocam.

That's great.  Too bad Museo has a rough, grainy, blotchy look to me.

>...but then again you could also just print on
>Epson Luster.  The dmax is only around 2.0...
>but the prints still look pretty good.

Is that one of those "RC" type papers?

It is ironic that RC papers may be the best solution.  I wonder what the
interior of those papers is.  My reading indicates that lignin is not, in
itself, acidic.  It is only when it is attacked by oxygen and other gasses
that it breaks down into components that are acidic.  I wonder if the RC
papers can be relatively cheap but long lasting because they are sealed.

Shame I don't like the RC look either.  An acid-free EAM would solve a lot
of problems here.

Paul
http://www.PaulRoark.com

Re: [Digital BW] Piezotone/Ultrachrome blacks was MIS inks - are they really pure pigment?

2002-10-04 by Robert Morrison

On 10/3/02 11:28 PM, "Paul Roark" <paul.roark@...> wrote:

> Robert wrote:
> 
>> The rather disappointing thing about the matte black ultrachrome ink is how
>> poor it performs (dmax) on every paper other than EAM.
> 
> I don't get it.  Epson comes up with some hot new technology that raises the
> bar for image permanence and blackness for a black ink -- but only on a
> paper that Wilhelm says has so much acid in it that it turns unacceptably
> yellow in 30 years.  Don't the paper and ink departments at Epson talk to
> each other?

Ah yes...the genius of Epson.

> 
> That would be nice.  The Somerset I have used just doesn't have the
> smoothness of EAM that I like so much.

Put at least it would be some variety.

>> I just coated an Ultrachrome print on Museo today.  The dmax went
>> from a very poor 1.48 to silver-like 2.13 as measured by my spectrocam.
> 
> That's great.  Too bad Museo has a rough, grainy, blotchy look to me.

It is still rough, but not at all grainy or blotch after it is coated.  You
can get the same results on Eclipse...and can use the smooth side.  In fact
my coating now works well on Photorag, EAM, Somerset, Legion Photo Matte,
Merlin, etc...all with better than 2 dmax...take your choice...but it still
requires an extra step.  We need to be able to get decent matte prints
without coating as well.

 
>> ...but then again you could also just print on
>> Epson Luster.  The dmax is only around 2.0...
>> but the prints still look pretty good.
> 
> Is that one of those "RC" type papers?

Yes, its E-surface.
 
> It is ironic that RC papers may be the best solution.  I wonder what the
> interior of those papers is.  My reading indicates that lignin is not, in
> itself, acidic.  It is only when it is attacked by oxygen and other gasses
> that it breaks down into components that are acidic.  I wonder if the RC
> papers can be relatively cheap but long lasting because they are sealed.

I think they are plastic...no acid there.

> Shame I don't like the RC look either.  An acid-free EAM would solve a lot
> of problems here.
> 
What about Legion Photo Matte?  I don't think it does well with the
Ultrachromes...but it is acid free and has a smooth surface...probably does
ok with the FS/VM black.  It is brightened like crazy, though.

Robert

Re: [Digital BW] Piezotone/Ultrachrome blacks was MIS inks - are they really pure pigment?

2002-10-04 by Paul Roark

Robert wrote:


> ...
>What about Legion Photo Matte?  I don't think it does well with the
>Ultrachromes...but it is acid free and has a smooth surface...
>probably does ok with the FS/VM black.  It is brightened like
>crazy, though.

I've had a box of LPM for some time, so the other day, in my frustration
with EAM, I pulled it out to take a second look.  The black with VM/FS-K is
about 1.60 -- not as good as the old EAM, but about the same as the new
batch of EAM that I sent back as "defective."  (My new roll of EEM is
better, but not as good as the best samples.  I guess they all probably vary
a bit.)

However, LPM still does not get the nice smooth tones and transitions of
EAM.  Also, I noticed that I could not use the "Back Light Film" paper
setting.  It flooded the 100% patch and resulted in a Dmax that was less
than the PQIJ paper setting -- more ink means lower Dmax in this case.  The
paper is really dense.  I'd guess it is loaded with calcium carbonate
buffer.  I've read that some papers are fully 30% filler.  I'm not sure
printing on limestone is the answer.

Paul
http://www.PaulRoark.com

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